Dispersive Solid Phase Extraction Headspace Sampling in Gas ChromatographyMass Spectrometric Analysis of Volatiles: Application to Separation of Polycyclic Aromatic Hydrocarbons
نویسندگان
چکیده
منابع مشابه
QuEChERS Method Followed by Solid Phase Extraction Method for Gas Chromatographic-Mass Spectrometric Determination of Polycyclic Aromatic Hydrocarbons in Fish
A gas chromatography equipped with mass spectrometer (GCMS) method was developed and validated for determination of 16 polycyclic aromatic hydrocarbons (PAHs) in fish using modified quick, easy, cheap, effective, rugged, and safe (QuEChERS) method for extraction and solid phase extraction for sample cleanup to remove most of the coextract combined with GCMS for determination of low concentratio...
متن کاملDetermination of Some Polycyclic Aromatic Hydrocarbons in the Caspian Seawater by HPLC Following Preconcentration with Solid-Phase Extraction
A solid-phase extraction (SPE) method for sample clean-up and preconcentration followed by reversed-phase high-performance liquid chromatography (RP-HPLC) with uv detection is reported for determination of polycyclic aromatic hydrocarbons (PAHs) in the caspian seawater. A good resolution was obtained using acetonitrile:water (40:60) as mobile-phase for separation of these compounds. The eff...
متن کاملCooling/heating-assisted headspace solid-phase microextraction of polycyclic aromatic hydrocarbons from contaminated soils.
A simple, low-cost, and effective cooling/heating-assisted headspace solid-phase microextraction (CHA-HS-SPME) device, capable of direct cooling the fiber to low temperatures and simultaneous heating the sample matrix to high temperatures, was fabricated and evaluated. It was able to cool down the commercial and handmade fibers for the effective tapping of volatile and semi-volatile species in ...
متن کاملNatural cotton fibers as adsorbent for solid-phase extraction of polycyclic aromatic hydrocarbons in water samples.
A natural material, cotton fiber, has been applied as a solid-phase extraction (SPE) adsorbent for sample preparation for the analysis of polycyclic aromatic hydrocarbons (PAH) in water samples using high-performance liquid chromatography. The cotton fiber was used directly without any chemical modifications, which avoided a complex synthesis process and consumption of a large volume of organic...
متن کاملTransformation of polycyclic aromatic hydrocarbons during sampling.
Individual PAH are shown to undergo chemical transformation when exposed to gases such as NO2, O3 and SO3. The possibility of artifact formation during sampling in stacks and in ambient air is discussed. PAH on soot, formed in a smoke gas generator, and exposed to NO chi and SO chi in a thermostated oven were degraded as a result of the sampling technique. Addition of NO2 (1 ppm) or gaseous HNO...
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ژورنال
عنوان ژورنال: Journal of the Brazilian Chemical Society
سال: 2018
ISSN: 0103-5053,1678-4790
DOI: 10.21577/0103-5053.20180198